Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides. A 40% thermal expansion mismatch between the austenitic stainless steel and ferritic base metal produces a signi. For stainless steel etching use solid ferric chloride chemical 1 kg. In its essence, stainless steel is a steel alloy composed mainly of iron with the addition of chromium minimum of 1012%. Apr 14, 2014 the basic method for acid metal etching is to apply protection to the areas of a metal surface, either to the whole area or just to the areas that are to remain unaffected. Methods for post fabrication and welding cleanup of stainless steel are well documented. These microconstituents are detrimental in stainless steel welds because they lead to weld decay. The wrc92 diagram can be used as a general guide to maintain a desirable solidification. Acid cleaning is the process used to remove various types of dirt buildup, discolouration, and tarnish from masonry or metals. Leave the steel plate in the etching acid until the lines are cut to the depth you want. Its more commonly used to etch copper, but it also works well to etch stainless steel. For etching duplex and 300 series stainless steels. By comparing different etchants and measurement practices, it was realized that etching with modified beraha followed by computerized image analysis ia was the.
A reference sample was produced by beadonplate gastungsten arc welding of a type2507 sdss plate. A discussion started in 2001 but continuing through 2020. Chemical and electrochemical etching of stainless steel. Austenitic or 300 series stainless steels typically have higher chrome as well as a significant amount of nickel e. This will be a basic tutorial on how to acid etch metal with ferric chloride. Etching solutions for steel, stainless, aluminum and other. It explains how hydrogen embrittlement occurs in stainless steel. How to solder, braze and weld stainless steel to copper in. Stainless steel can be etched using ferric chloride mixed with water, which creates a hydrochloric acid. Methods to avoid material sensitization during welding for. Pdf effect of etching methods in metallographic studies of. Stainless steel etching is a highly accurate process that produces parts with a high level of complexity with no mechanical stress placed on the material. By comparing different etchants and measurement practices, it was realized that etching with modified beraha.
Post weld cleaning and finishing of stainless steels. Then the pattern to be etched is photographed onto it. However, for type 316 stainless steel, a ten minute etch in a boiling 50% by volume sulfuric acid plus 120 gliter copper sulfate solution instead of the above test condition should be utilized. I get a deep etch using nacl,hcl and a welding inverter. The solution that works for aluminum is also a three part mixture composed of the following. I am using a tig at 55 amps on a 115 circut with 17 cfh of argon. This test is to be used in the same manner as the oxalic acid etch test astm a262a for stainless steels, but gives superior results for ferritic.
Effect of temperature in hydrogen embrittlement in stainless steel, and fusion in inox steel. Acid cleaning is common for keeping brick walls, concrete footpaths, and metallic building structures looking clean and new. Why passivate stainless steel and what happens if you dont by. The location, extent and magnitude of the cracking is dependent upon procedure characteristics as well as composition. Sometimes the naked eye is all that is needed to inspect the weld profile but viewing at 3x to as high as 20x can help see even more features of the weld as long as the polish is fine enough so that grinding scratches do not. The metallurgical, physical and chemical changes caused by the welding process affect the corrosion resistance of the weld. Copper sulfate is better suited to etching mild steels than stainless steel. This is a very common joint in the brewing and distilling industry, and knowing the proper way to join these. I read that a solution of 4% to 10% citric acid and water heated to 150 degrees f will remove any iron from the stainless steel surface and after rinsing with clean water it will promote a good chromium oxide.
The parts of the metal to be etched are then either not covered or the protected material is scratched off from it using tools such as an etching needle. However, stronger bases will cause cracking or etching corrosion. Both the pipe and flange are made of aisi 321 stainless steel. Use after nital etch, it will highlight the weld nugget and make it easier to see. Jan 07, 2015 acid cleaning is the process used to remove various types of dirt buildup, discolouration, and tarnish from masonry or metals. The nickelcopper alloys, typified by monel alloy 400 have excellent resistance to hydrofluoric acid corrosion. Cracking occurred in welds containing 83% ferrite and hydrogen levels of 11. The bubbles impede the etching process, but they can also create interesting designs if left alone. Mar 16, 2019 chromium is used in stainless steel to prevent corrosion, when you heat stainless between 425870 c 8001600 f for prolong periods of time the chromium can diffuse away from the surface and form chromium carbides, which will make the steel no longer stainless.
Traditionally, the cracks have been observed around the spot nugget in welded temperature. Sensitization response of weld joints in stainless steel. Basic understanding of weld corrosion asm international. The investigation revealed that both the circumferential and seam welds were in sound conditions, namely no evidences of sensitization, lack of weld penetration, and voids or porosities. This article explains all about hydrogen embrittlment in stainless steel. You could buy a lot of scotch pads and pickling past and pay a very enthusiastic 15yo kid for a long time with that kind of money. The flange was circumferentially welded to the pipe which is seam welded. I usually use vinyl resist but rapidmask works too. Avoiding cracking in austenitic ss weld overlays american. It is possible to avoid these problems by selecting the right alloy process and parameters to minimize dilution and keep the resultant crni equivalency ratio above 1. Stainless steel supplied by reputable manufacturers, stockholders or fabricators will normally be clean and contamination free. Cracking phenomenon in spot welded joints of austenitic. What are the chemical to etching fast stainless steel and what is the process involved in it.
Actually, these cracks are developed due to incomplete melting and inappropriate electrode pressure, which causes an expulsion of molten metal. Crsegregation by spinodal decomposition and gphase precipitation were observed in. The test is used for acceptance but not for rejection of material. Optional 2nd stage for staining low carbon mild steel welds. Slicing, dicing, polishing, etching, and visual inspection are basically all that is involved with a macro etch test.
Passivating stainless steel with nitric or citric acid. For welds that have not been properly cleaned after completion, this is normal, par. Approaches to determining ferrite fraction % and ferrite number fn were examined for super duplex stainless steel sdss welds. Oxalic acid etching as per the astm 262 practicea 8 showed the step structure in beataffected zone of asreceived stainless steel of both the pipes. Iron contamination and rust staining on stainless steel. Passivation of stainless steel after welding cougartron. However, the cathodic behavior of the austenitic weld deposit may increase the susceptibility for stresscorrosion cracking scc in the haz of the highstrength steel. This leads to both the heat affected zone haz and the weld metal corroding faster or slower than the base metal. The stainless is first coated with a photosensitive mask material. Failure of stainless steel welds due to microstructural.
The microstructures were revealed by electrochemical etching, which was carried out with oxalic acid 10% 100ml distilled. Electrochemical stainless steel weld cleaning benefits. Using pickling and passivation chemical treatments to. I am facing problem in stainless steel etching process. Stainless steel sheet metal or shim stock is commonly acid etched in the industrial version of the chemical milling process. Hydrogen cracking of ferriticaustenitic stainless steel. In my case i was building a homemade pot still and needed to bond the stainless steel tri clamp ferrules to a 2. Jul 30, 2015 my question is, after i have it welded can i use a citric acid bath to passivate the stainless steel to prevent the welds from corroding. Post weld cleaning and finishing of stainless steels introduction. Ferrite content measurement in super duplex stainless steel welds.
The wrc92 diagram can be used as a general guide to maintain. Carbides present in the haz of an austenitic stainless steel dissolve on heating and reform on cooling during the welding heat cycle. One issue is whether the heat tint discolouration in the heataffected zone of stainless steel welds should be removed. The basic method for acid metal etching is to apply protection to the areas of a metal surface, either to the whole area or just to the areas that are to remain unaffected.
How to etch stainless steel with acid our pastimes. Unfortunately, these new precipitates form preferentially as chromium carbides on the grain boundaries, depleting chromium from the region immediately adjacent to the boundary. Solidification cracking is a significant problem during the welding of austenitic stainless steels, particularly in fully austenitic and stabilized compositions. Stainless steel etching is the process of using corrosive chemicals to etch complex shapes from sheets of stainless steel metal. Surfaces must be free of grease and dirt before using these acid treatments. The passive condition on the surface of the stainless steel is obtained. Metallographic stainless steel etchants etching stainless steels can be somewhat difficult due to the anticorrosive nature of stainless steel. Whether you put the steel plate in the etching acid faceup or face down, suspend it off the bottom of the container in some fashion. For etching 300 series stainless steel and hastelloy superalloys. I am trying to weld a stainless steel fitting to 58 stainless barstock that has been gundrilled 38 inside. The acid will slowly eat away layers of the metal, and it will flake off leaving exposed areas that create a design. How to solder, braze and weld stainless steel to copper.
Both pickling and passivation are chemical treatments applied to the surface of stainless steel to remove contaminants and assist the formation of a continuous chromiumoxide, passive film. When exposed to normal atmospheric conditions air, chromium will react with oxygen and create a protective layer on the surface of the alloy. Ferrite content measurement in super duplex stainless. Solidification cracking in austenitic stainless steel welds. Banes, astro pak corporation to insure having the maximum corrosion resistance that austenitic stainless steel has to offer, the stainless steel surface must be in a passive state. The steel and filler metal should be selected with as low a ferrite content as possible, say 1 to 3% for best charpyv test results. It is also explained that how to test the damage due to hydrogen embrittlement in stainless steel. Mar 05, 2020 the bubbles impede the etching process, but they can also create interesting designs if left alone. Gotta cut down pressure to 40psi on a pressure pot. Stainless steels, such as 316, suffered severe transgranular corrosion. Everything looks great after grinding and polishing the weld smooth,but after pressure testing to 3500 psi with water in the tube,i keep getting hairline cracks allowing water seepage.
Hot cracking in stainless steel welds is caused by lowmelting eutectics containing impurities such as s, p and alloy elements such as ti, nb. Stainless steel etching takes stainless steel laminated with a photoresist mask printed with a cad image of the component, which is then selectively etched with ferric chloride, a safe to use, recyclable etchant chemistry. While 304lnp i remained to be step even after ageing for longer hours such as for 8000 and 800hrs at. The factors of hydrogen embrittlement and ways to prevent it is. I wont get into too many details on stenciling and the graphic design side of things as that would be a whole other tutorial. Carbonic acid corrosion can lead to failures at the ph 210 range in onephase or twophase media, leading to general corrosion, local corrosion in the form of pitting, corrosionerosion, and a special type of failure chalky failure. Topic welding industry technical discussions etching stainless steels by kam date 10092002 20. Cracking initiated at the root of the weld and propagated in a transgranular manner through delta fer rite. Etching stainless steel can be difficult but if you thoroughly clean it then get it warm about 30 deg c you gan get a reliable result. The programme sought to generate cracking data for sma welds, in 22%cr duplex stainless steel, for which the consumable hydrogen level had been determined using the vhe method.
This situation can happen in otherwise corrosionresistant alloys, when the grain. Hot cracking resistance of austenitic stainless steel weld. It also works with a wider range of resist materials than pure acids do. This type of failure is characteristic of co 2 failure. Intergranular corrosion of nonsensitized austenitic. For stainless steels stick with the following mixture. Only stainless steel wire brushes should be used on stainless steel. Stainless steel offers strong resistance to weak bases in both high concentrations and hightemperature environments. If youre building a project that requires you to join a copper and stainless steel part this article will teach you how to do it. The use of non stainless steel processing and handling equipment is a frequent source of contamination. In july 1996, the laboratory supervisor at a major stainless steel processing facility sustained a severe eye injury when a mixture of 25ml concentrated hydrochloric acid, 25ml concentrated nitric acid and 50ml isopropyl alcohol burst through the top of the storage bottle and splashed into his right eye. Solidification cracking of austenitic stainless steel overlays is a common problem in cladding ring grooves and other carbon steel features. It is possible to avoid these problems by selecting the right alloy process and parameters to minimize dilution.
This is particularly important for repairs of industrial components made of austenitic stainless steel. We tested welds in 4 chromoly, all types of stainless steels like 321, 410, 177, a286, etc, all kinds of nickel alloys like inconel 625, 7c, 750, and 718, aluminum alloys like 6061 and cast aluminum like a356, magnesium alloys like az31b and also mag castings, titanium alloys like cp, 6al4v, and cobalt alloys like haynes 188. Why passivate stainless steel and what happens if you dont. A resist is applied to the metal, then the metal is dipped into the acid until the desired effect is achieved. In july 1996, the laboratory supervisor at a major stainless steel processing facility sustained a severe eye injury when a mixture of 25ml concentrated hydrochloric acid, 25ml concentrated nitric acid and 50ml isopropyl alcohol burst through the top. Oxalic etch test oxalic acid etch test is a rapid method of screening specimens of certain stainless steel grades which are essentially free of susceptibility to inter angular attack associated with chromium carbide participates.
These items should not show rust staining, unless contamination is introduced. The beneficial role of higher austen ite levels in duplex stainless steel weld metal in terms of decreasing hydrogen cracking susceptibility was associated with a lower diffusible hydrogen content in tes t welds. Conversely, for best creep resistance an h grade steel should be selected and rutile or acid rutile electrodes and acid submerged arc fluxes should be used. There are matching filler metals available for most of the austenitic range of alloys, the exceptions being that there is no. For types 430, 430 ti, 430 nb, 434, 444, and 446 ferritic stainless steels, the test consists of etching a polished sample for five minutes in a boiling 60% by volume sulfuric acid plus 120 gliter copper sulfate solution. The same test method can also be applied to types 304 and 316 austenitic stainless steels. Apply at room temperature with a cotton swab or immerse the part in the solution. Three different etching methods are used to uncover the ferriteaustenite structure and precipitates of secondary phases in stainless steel 22. For haz hydrogen cracking to occur, it is necessary for the hydrogen to migrate into the heat affected zone, which takes time. Failure investigation of 321 stainless steel pipe to. Failure investigation of 321 stainless steel pipe to flange. The weld metal heataffected zone thermal history plays an important role in controlling fissuring tendency in the.
Hot cracking resistance of austenitic stainless steel weld metals. Nevertheless, they are prone to appear in the heat affected zone haz microstructure of stainless steel welds. Causes and prevention of corrosion on welded joints. Hydrochloric acid is an exception to the general acid resistance of stainless steel and should be avoided. My question is, after i have it welded can i use a citric acid bath to passivate the stainless steel to prevent the welds from corroding. It contains nitric acid and is more effective than rust removal jelly. Hydrofluoric acid, hydrogen fluoride and fluorine are less corrosive to many metals and alloys than their own halide counterpart. Stainless steels resist corrosion best if they are clean and smooth. Hydrogen cracking of ferriticaustenitic stainless steel weld. Electrochemical weld cleaning the fastest and safest way to clean stainless steel welds electrochemical weld cleaning is a process by which postweld impurities such as rust, heat tints, and discoloration are removed from metal surfaces under the effect of mild electrolytic fluids and a weak electrical current. Cases of uniform corrosion across the base metal and weld metal, or the base metal corroding and the weld metal remaining unaffected. Weld oxidation welds will frequently exhibit rusting along the edges as shown in figures 1 and 2. Pdf effect of etching methods in metallographic studies. Hydrogen cracking in duplex stainless steel weld metal.
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